If it was a realistic world, then it would be great to be a villainess (as long as it wasn't an ultra-misogynistic society like in Ebony). But since Otomege and Shoujo novels about fantasy medieval aristocratic societies aren't even close to having realistic political dynamics, it would suck to be a villain.
However, if the villainess has high specs... then why not? You can just power you way through all the world correction from your abilities alone.
But... it looks like she's never played an otomege. But she has read them right? Aren't all villainess the same? Bully the Heroine? Isn't that it? I mean, a real villainess would be different, but an Otomege villainess is basically just the school bully.