This isn't even friend zoned. There has to be another possible category for the friend zone to exist. So this is a tad bit better than friendzoned. There still is a chance. He just has to enlighten her to the world of romance first.
On a side note. She is just plain ignorant of anything involving the feeling of love. She can think of sinarios, but the emotion itself is totally lost on her. She is destined to be a shounen dense harem MC in the future for sure.