Yankee wa Isekai de Seirei ni Aisaremasu. - Vol. 4 Ch. 28 - ...Maybe.

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It's a similar principle to ice cubes exploding in a deep fryer. "Hot enough to melt rock" is enough to instantly melt and boil ice into steam, at which point it will expand explosively. It's so fast it wouldn't actually need to be contained.
 
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Enjoyed the silly take on physics miced with magic! Thank you for the release.
By the way, how many credit/splash pages do you guys need? It's getting almost silly at this point. lol
 
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The wind spirit did told him that there was a barrier around the temple...
 
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I love how they toss the "use hot and cold in rapid succession!" shounen gimmick out there but skipped the obligatory (pseudo-)science explanation because Zero is an idiot ...not very studious and would have to go totally out of character to explain it.

It's the "something something effect", indeed.
 
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It's basic science, don't throw water/ice into/on hot things. This is because steam is created faster than it can escape, causing pressure and things to explode.

There's a few videos where people tried to fry food on rocks, moisture trapped in rocks either cracked the rock or made an explosion. This works the other way around if you pour or place things cold quickly on the rock.

Anyway, it was explained the barrier will stop humans out but keep spirits in, obvious now he is a some sort of great spirit since he can be seen by humans and can see chibis spirits.
Zero probably will get stuck there or find a way to dispell the barrier.
 

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