Well, she's there because Arthur tried to change destiny, as Guinevere warned him; And they also confirmed that the Camelot Knights weren't aware of her.
On the last panel we see Tristan taking a more defensive position after she revealed to be a Demon, but she looks slightly disappointed, I mean, she just told her that she was not on Camelot's side, and he still treated her as an enemy, just because she's a Demon. (Even thou Meliodas is a Demon himself smh).