Because she somehow feels "impure" for having had sex with Yuu—which is partly why she has a bad reputation at her school. Incidentally, he has a similar mindset. These concepts of purity reinforced in both of them the feeling of having done something "forbidden", especially since having sex in love hotels while underage is illegal in Japan —and worldwide.
That's why she sees sex as both positive and necessary, and at the same time forbidden and impure. They both act as if they've completely lost their innocence. This is partly why neither of them told anyone about the sexual aspects of their relationship, including Hikari. When Yami finally told Hikari and her friends, she distorted the events and portrayed herself as a slut when in reality she had only had sex with her boyfriend, whom she loved.
This also explains why her proposal to live together in chapter 28 was almost a marriage proposal, and why Yuu also wanted to commit to Ayami for life. Their romance is partly tragic because both of them—though much more so her—failed to communicate this to each other.
Hence, Yami almost put on Unravel while having sex with Yuu. This is why it's so important that Hikari does NOT share this view of love and sexuality, and why she feels ashamed of still being a virgin (chapter 5). This is also why she fell in love with Yuu precisely because he had gained sexual and emotional experience with Aya.