So let me get this straight, the evil Duke's plan to get a daughter as the next Queen is:
Step 1: Get Daughter #1 happily engaged to the Crown Prince, such that unless there is outside interference, she will definitely become the Queen just like he wants.
Step 2: Send in Daughter #2 to disrupt the engagement he orchestrated in Step 1 of the plan.
Step 3: Order Daughter #1 to arrange the assassination of Daughter #2, because she is disrupting Step 1 of the plan in accordance with Step 2 of the plan. This should remove Daughter #2 while linking Daughter #1 to a crime that would have her deposed should it be revealed.
Step 4: ???
Step 5: Profit!